HAZMAT First Responder Operations Test Q&A [2023]

In this post, we will be discussing HAZMAT First Responder Operations Test questions and answers that are absolutely FREE to view.

By studying the material covered in the practice test below, you will be well prepared to take the actual HAZMAT First Responder Operations test & become a certified HAZMAT First Responder.

HAZMAT First Responder Operations Test Questions and Answers

The below Q&A covers a wide range of topics, including Hazard Identification and Classification, Spill Containment and Control, Hazardous Materials (HAZMAT) Awareness, etc…

NOTE: All HAZMAT First Responder Operations Test questions and answers are checked twice before publishing them to you. So, please do share as well if it helps.

HAZMAT First Responder Operations Test questions and answers

 

HAZMAT First Responder Operations Test Questions and Answers – Sample Paper 1

Find the right Q&A to the sample paper 1 below:

Q. Substances or materials in quantities of forms that may pose an unreasonable risk to health, safety, or property when transported, stored, or used in commerce is a definition for a:
Ans: Hazardous material

Q. When dealing with a radioactive incident involving a leak or spill, what exposure guidelines should hazardous materials first responders use to minimize radioactive contamination?
Ans: Time, distance, and shielding

Q. The four-digit number appearing on a placard or an orange panel of a tank car is the:
Ans: UN product identification number

Q. The NFPA 704 systems for identifying hazardous materials give:
Ans: The general hazard and degree of severity

Q. A number 4 in the blue quadrant of the NFPA 704 system indicates that there is _ risk on this category from the chemical involved.
Ans: A severity

Q. A white quadrant in the 6 o’clock position of the NFPA 704 system is used to indicate:
Ans: Special hazards

Q. The fact that a product is water reactive would be indicated in the _ quadrant of the NFPA 704 system:
Ans: White

Q. For materials in Hazard Class 8 (corrosive), a DOT placard is required if the gross weight is in excess of:
Ans: 1000 lbs

Q. UN/DOT placards indicate general hazard recognition by:
Ans: Giving the UN hazard class number

Q. A bill of lading contains valuable information about the origin of the product and is the type of shipping paper used when transporting a product via:
Ans: Highway truck

Q. The DOT placarding system requires a vehicle carrying nonflammable compressed gas to display a placard colored:
Ans: Green

Q. A container of flammable solids would receive a UN label or placard with a hazard classification number of:
Ans: 4

Q. Using the UN/DOT labeling system, a flammable liquid would receive a hazard classification of:
Ans: 3

Q. Physical data, chemical name, exposure limits, health hazard data, and special precautions are all part of the:
Ans: Safety Data Sheet

Q. Referring to the U.S. military marking system for hazardous materials, the symbol for a mass fire hazard is:
Ans: #3 in a triangle

Q. The PRIMARY hazard for an oxidizer in a fire is its ability to:
Ans: Accelerate combustion

Q. The DOT Hazard Class 2 indicates:
Ans: Nonflammable gases

Q. According to the NFPA 704 system, the most dangerous chemical would have a placard showing which of the following number sets?
Ans: 4, 4, 2

Q. Under SARA title 3, some facilities are required to have SDS information. The PRIMARY consideration in determining whether a facility is required to have an SDS is whether the facility:
Ans: Has chemicals that are NOT consumer quantities

Q. A document developed by the manufacturer listing specific hazards of a product is called:
Ans: The Safety Data Sheet

Q. The number _ would be shown in the flammability quadrant of the NFPA 704 system for a material that must be moderately heated before ignition can occur, and on which water spray may be used to extinguish a fire:
Ans: 2

Q. During a suspected terrorist event, the outward warning indicator(s) that responders should be alert to is/are:
Ans:
-Strong chemical odors without apparent reason
-Unexplained patterns of illness or death
-Unusual containers that are out of place with the surroundings

Q. A tractor-trailer hauling gasoline should display a placard with a Hazard Class of:
Ans: Red, 3

Q. _ is placed on highway transport vehicles to identify the contents:
Ans: A placard

Q. The person responsible for control of the air-bill papers is the:
Ans: Pilot

Q. With respect to the U.S. military marking system for hazardous materials, which of the following IS NOT one of the three special hazard symbols?
Ans: Apply No Dry Chemical (fire extinguisher discharging chemical onto a fire with a diagonal slash within the circle)

Q. DIRECTIONS: Read the following statements, then select your answer from A-D below:
1.) In urban or suburban locals, hazardous materials can be found in service stations, hardware stores, and doctors offices
2.) In rural areas, hazardous materials can be found in agricultural stores or co-ops, farm buildings, and residences
3.) The size of the community determines the potential for hazardous materials
Ans: Only statements 1 and 2 are correct

Q. DIRECTIONS: Read the following statements, then select your answer from A-D below:
1.) EPA labels on pesticides must contain one of the signal words, DANGEROUS/POISON, WARNING, or CAUTION
2.) The word WARNING is used on labels for packages containing highly toxic materials
3.) The signal words EXTREMELY FLAMMABLE are also displayed if the package contains a flash point below 80 degrees F
Ans: Only statements 1 and 3 are correct

Q. The manufacturing and labeling of pesticides is regulated by:
Ans: EPA (Environmental Protection Agency)

Q. Where are pipeline owners required to place pipeline markings (and where can first responders expect to find them):
Ans: At any place the underground pipeline crosses a mode of transportation

Q. Of the following, which is the quickest available source of SDS for first responders at a hazardous materials incident?
A. The supplier of the material
B. The Local Emergency Planning Committee (LEPC)
C. CHEMTREC
D. OSHA
Ans: C

Q. DIRECTIONS: Read the following statements, then select your answer from A-D below:
1.) If placards are clearly displayed on the transportation mode, shipping papers are not required
2.) If a transportation mode is NOT carrying hazardous materials, there is no requirement for specific information to be provided on shipping papers
3.) Shipping papers must contain the proper name of the chemical or its Hazard Class
Ans: Only statement 2 and 3 are correct

Q. DIRECTIONS: Read the following statements, then select your answer from A-D below:
1.) When carrying hazardous materials, a transportation mode must carry shipping papers
2.) Shipping papers may include a packing group number listed as 1, 2, or 3
3.) The higher the packing group number, the more dangerous the chemical is
Ans: Only statement 1 and 2 are correct

Q. Who is responsible for care and control of billing of lading?
Ans: Driver

Q. DIRECTIONS: Read the following statements regarding hazardous materials recognition and identification, then select your answer from A-D below:
1.) Nerve agents were designed for one purpose, to kill people
2.) Blood and choking agents, while being terrorism agents, are also common industrial chemicals
3.) Biological agents are the easiest of the categories of warfare agents to make
Ans: All three statements are correct

Q. DIRECTIONS: Read the following statements regarding hazardous materials recognition and identification, then select your answer from A-D below:
1.) Federal public buildings are prime targets for terrorist attacks
2.) Social security buildings would be an exception to statement 1 above
3.) Virtually all terrorist attacks are directed toward public buildings
Ans: Only statements 2 and 3 are correct

Q. Using the nuclear, biological, and chemical (NBC) classification, which of the following IS NOT considered a chemical warfare agent?
Ans: Ricin

Q. Given the product name, you can find the four-digit UN/DOT number assigned by referencing the following, EXCEPT:
Ans: Safety Data Sheet

Q. Which of the following WOULD NOT be used to determine the name of a hazardous material located in a facility?
Ans: NFPA 704 diamond

Q. When referencing the DOT Emergency Response Guidebook, if a chemicals name IS NOT highlighted, the next step is to proceed to the _ section:
Ans: Orange

Q. The chemicals listed in the highlighted type in the DOT Emergency Response Guidebook were selected because:
Ans: They present a poison inhalation hazard

Q. The DOT Hazard Class 2 consists of:
Ans: Gases

Q. The DOT Hazard Class 3 consists of:
Ans: Flammable liquids

Q. The DOT Hazard Class 4 consists of:
Ans: Flammable solids

Q. The DOT Hazard Class 5 consists of:
Ans: Oxidizers

Q. The DOT Hazard Class 6 consists of:
Ans: Poisons

Q. The DOT Hazard Class 7 consists of:
Ans: Radioactive substances

Q. The DOT Hazard Class 9 consists of:
Ans: Miscellaneous

Q. The recommended course of action for fighting a small fire involving a substance identified by the UNNA ID number 2553 can be found in the _ section of the Emergency Response Guidebook:
Ans: Orange

Q. When using the table of isolation distances in the Emergency Response Guidebook, a large spill is defined as a quantity greater than:
Ans: 55 gallons

 

HAZMAT First Responder Operations Test Questions and Answers – Sample Paper 2

Find the right Q&A to the sample paper 2 below:

Q. The recommended shape of the isolation zone for a chemical spill or release is:
Ans: Circular

Q. The statement, “People inside a building should remain inside until the danger passes” best describes:
Ans: Shelter-in-place

Q. Scene control at a terrorism incident may present unique challenges for the responders. In particular:
Ans: The terrorists may be on the scene waiting for responders before striking again

Q. The route of exposure that is the MOST COMMONLY associated with causing ill effects, both acute and chronic, is:
Ans: Inhalation

Q. The taking of hazardous materials into the body through the undamaged skin and the eyes is called:
Ans: Absorption

Q. When considering personnel protection, remember that the MOST COMMON route of exposure for an emergency responder is:
Ans: The respiratory system

Q. Work uniforms that provide minimal protection BEST defines EPA Level _ protection:
Ans: D

Q. “The highest level of protection is needed, but lesser chemical is required for the skin” BEST defines EPA Level _ protection:
Ans: B

Q. The type of breathing system that can not be utilized in an oxygen-deficient atmosphere is:
Ans: An air-purification respirator

Q. Self-contained breathing apparatus (SCBA) and supplied air respirator (SAR) are two types of:
Ans: Atmosphere-supplied devices

Q. Diking, damming, and diverting are _ options available for _ control:
Ans: Defensive, Spill

Q. As a first responder trained to the operations level, which spill control tactic(s) can be conducted?
Ans:
-Absorption
-Dilution
-Vapor suppression

Q. _ is the controlled burning of a liquid or gas to reduce or control the pressure and/or to dispose of the product:
Ans: Flaring

Q. A/an _ is recommended to include details such as site information analysis of site hazards, risk analysis, PPE, and a work plan:
Ans: Site safety plan

Q. The piping for the _ is connected outside of the tank, usually on the end, with a manhole on top of the tank:
Ans: IM 102

Q. The statement “Keep Away from Waterways” is found on a pesticide label. This statement is referred as a/an:
Ans: Hazard statement

Q. A recon team is sent to observe a tank truck that have rolled over. The team reports that the vehicle is an MC 312. The container most probably contains a:
Ans: Corrosive liquid

Q. In response to an incident involving a jackknifed tractor-trailer, you arrive and size up the situation. From your position, you only have a side view of the tractor-trailer. You know it is an:
Ans: MC 331

Q. A carboy may be used for transporting materials containing:
Ans: Corrosives

Q. The proper cargo tank truck to carry a shipment of sulfuric acid is an:
Ans: MC 312/DOT 412

Q. A cryogenic liquid tank car will have:
Ans: A double shell with insulation

Q. Which of the following IS NOT mandatory information found on a pesticide label?
Ans: NFPA 704 data

Q. When implementing tactical activities during a bomb event, responders should:
Ans: Be alert for secondary devices

Q. The rail car pictured below is what type of tank car?
Ans: Pressure tank car

Q. While surveying a hazardous materials incident scene, you notice yellowish vapors emitting from the cylinder. The driver of the vehicle carrying the cylinders tells you that they contain chlorine. As a responder trained to the operations level, one of the ways to verify chlorine could emit these vapors is to:
Ans: Contact CHEMTREC for assistance

Q. The intermodal tank that is designed for working pressures of 100 to 500 psi and usually transports liquified gases under pressure is known as an:
Ans: IMO Type 5

Q. The design pressure of an IM 101 portable tank is:
Ans: 25.4 to 100 psi

Q. An intermodal container that is capable of holding high-pressure gases 3000 psi or higher is a:
Ans: Tube module intermodal container

Q. Cylindrical packaging made of metal, plastic, or fiberboard used to transport solids or liquids BEST describes:
Ans: Drums

Q. _ interfere with oxygen exchange during normal respirations:
Ans: Asphyxiates

Q. _ is the minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air:
Ans: Flash point

Q. Determination whether a vapor will rise or fall is commonly referred to as:
Ans: Vapor density

Q. Chemicals that are classified as _ can cause a severe allergic reaction:
Ans: Sensitizers

Q. What would be the likely result of allowing a contaminated individual to lead the hot zone without being decontaminated:
Ans: The contaminants would likely be transferred to other personnel or equipment, resulting in secondary contamination

Q. The MINIMUM temperature at which a liquid gives off sufficient vapors to form an ignitable mixture, with air near the surface is called:
Ans: Flash

Q. MOST riot control agents are considered to be in DOT hazard class:
Ans: 6.2

Q. Pepper spray is considered an irritant. Which of the following IS NOT a symptom of irritant exposure?
Ans: Fluid in the lungs

Q. The concentration that SHOULD NEVER be exceeded is called:
Ans: TLV-C

Q. The measurement commonly used by OSHA is evaluating workplace exposure during an 8-hour period is:
Ans: PEL

Q. Which of the following resources are available for determining the concentration of a released hazardous material IN AN ENDANGERED AREA?
Ans: Monitoring equipment should be utilized =, keeping in mind that hazardous materials technicians are needed to operate this equipment.

Q. Defensive control techniques that operations-level personnel are permitted to engage in are:
Ans: Diking, damming, diversion, and retention

Q. A process by which a hazardous-liquid flow is redirected away from an area is called:
Ans: Diversion

Q. Diversion, diking, and retention are all techniques used in:
Ans: Confinement

Q. Actions taken to confine a product release to a limited area, performed remotely are considered to be:
Ans: Defensive strategies

Q. The zone where contamination has occurred or has the potential to occur, which requires established entry and exit control points, is known as the _ zone:
Ans: Hot/exclusion

Q. In level 1 incidents, the response team should be able to deal with:
Ans: A natural gas leak in an occupancy

Q. The safety officer notices a critical emergency condition at an incident. The safety officer should:
Ans: Intervene in the unsafe action

Q. The person who advises the incident commander of existing or potentially unsafe conditions, monitoring conditions of personnel, and compliance with standard operating procedures is the:
Ans: Safety officer

Q. At a hazardous materials emergency, the Operations section is responsible for:
Ans: Controlling the tactical portion of the incident

Q. “The individual responsible for establishing and managing the overall plan, developing an organization structure, and allocating resources” BEST describes:
Ans: Incident commander

 

HAZMAT First Responder Operations Test Questions and Answers – Sample Paper 3

Find the right Q&A to the sample paper 3 below:

Q. The first step and MOST IMPORTANT thing to accomplish upon arrival at a hazmat incident or suspected hazmat incident is:
Ans: Isolation of the area and prevention of entry

Q. When responding to a potential hazmat incident, the safest way to approach the scene is to:
Ans: Approach from uphill, and upwind, even if it requires a longer response time

Q. Dizziness, headache, nausea, vomiting, diarrhea, and decreased urine output are all signs of:
Ans: Heat exhaustion

Q. The highest level of protection from hazardous chemicals provided by chemical protective clothing is:
Ans: Level A

Q. A hazardous material is defined as a substance or material capable of posing an unreasonable risk to health, safety, and property. TRUE or FALSE?
Ans: TRUE

Q. The most critical parameter when selecting the appropriate level of chemical-protective equipment is:
Ans: Chemical compatibility

Q. “The process by which a chemical enters a protective suit through openings in the garment” BEST describes:
Ans: Penetration

Q. The physical destruction or decomposition of chemical protective clothing by a chemical action is called:
Ans: Degration

Q. “The chemical action involving the movement of chemicals, on a molecular level, through intact materials” BEST define:
Ans: Permeation

Q. “The physical destruction or decomposition of chemical protective clothing material due to exposure to chemicals, general use, or ambient conditions” defines:
Ans: Degradation

Q. The type of breathing system that CANNOT BE utilized in an oxygen-deficient atmosphere is:
Ans: An air-purification respirator

Q. Self-contained breathing apparatus and supplied-air respirators are:
Ans: Atmosphere-supplied devices

Q. When using air-purifying respirators, which of the following IS NOT an operational component that should be considered prior to use?
A. The supplied air line cannot exceed 300 feet
B. The appropriate cartridge/filter is selected prior to use
C. The concentration of chemical is known
D. Ambient air must contain at least 19.5% oxygen
Ans: A

Q. An advantage of using a Level A with supplied air respirator (Type 3) chemical vapor suit:
Ans: That it permits extended operations

Q. A/an ____ is recommended to include details such as site information analysis of site hazards, risk analysis, PPE, and a work plan:
Ans: Site safety plan

Q. A reference book intended to be carried in every emergency vehicle in the US is the:
Ans: DOT Emergency Response Guidebook

Q. If a chemical name is highlighted in the Emergency Response Guidebook, the table of initial isolation and protective action distances is found in the _ section:
Ans: Green-bordered pages

Q. Where would a first responder expect to find a dangerous cargo manifest?
Ans: Bridge or pilot house

Q. Which section of the Emergency Response Guidebook provides the fire, explosion, and health hazard information for the material identified by the first responder?
Ans: Orange-bordered pages

Q. The collection of evidence at a terrorist event is primarily the responsibility of:
Ans: Law enforcement

Q. Where would a first responder expect to find a waybill or consist?
Ans: Engine or caboose

Q. The lead agency during a terrorist emergency (crisis management) is:
Ans: The FBI

Q. Where would a first responder expect to find a air bill?
Ans: Cockpit

Q. The injury/reaction occurring at the point of initial contact with a substance is known as what?
Ans: Local toxicity

Q. A hazardous material is defined as a substance or material capable of posing an unreasonable risk to health, safety, and property. True or False?
Ans: True

Q. Which is not a consideration when selecting Personal Protective Equipment (PPE)?
Ans: Color of the suit

Q. Some of the hazard diamonds used on National Fire Protection Association (NFPA) placards display numbers. Which number represents the highest level of danger?
Ans: 4

Q. The Resource Conservation and Recovery Act (RCRA) includes details for the generation, storage, treatment, and disposal of all hazardous waste (i.e. “Cradle to Grave”). True or False
Ans: True

Q. With regard to hazmat. Federal law requires
Ans: vehicles containing quantities of hazmat must display a hazmat placard

Q. Three goals of hazmat response?
Ans: Life, Environment, Property

Q. ______ is the flow of a hazmat through zippers, pinholes, or other material imperfections found in chemical protective:
Ans: Penetration

Q. Common hazards found at a car accident are all except
Ans: abundance of rescue personnel

Q. In an ambient atmosphere, 24 percent oxygen is considered a normal occurrence. True or False?
Ans: False

Q. While surveying a hazardous materials incident scene, you notice yellowish vapors emitting from the cylinder. The driver of the vehicle carrying the cylinders tells you that they contain chlorine. As a responder trained to the operations level, one of the ways to verify chlorine could emit these vapors is to:
Ans: Contact CHEMTREC for assistance

Q. What does the acronym BLEVE mean?
Ans: Boiling Liquid Expanding Vapor Explosion

Q. Name three NFA categories of hazardous materials
Ans: Thermal, Etiological, Mechanical

Q. Awareness level First Responders who witness or discover a hazardous substance release may initiate notification of authorities but may not take any further actions to stop the release. True or False?
Ans: True

Q. Tanker trucks transporting hazardous materials are required by law to display which of the following on each container?
Ans: Placards

Q. In a hazardous materials incident, the Emergency Medical Responder’s primary responsibility would be to use what?
Ans: Use personal protection

Q. What dispersion pattern is “a triangular-shaped pattern of a hazardous material with a point source at the breach and a wide base downrange”?
Ans: Cone

Q. What are the three sides of the reactivity triangle
Ans: Oxidizing agent (oxygen), Energy source (often heat), Reducing agent (fuel)

Q. If an area has a concentration of hazardous substance vapors above the Upper Explosive Limit (UEL), why won’t the vapors ignite?
Ans: The air is too rich

Q. Hazardous Material Technicians typically perform offensive actions during a hazardous materials release by attempting to stop the release. True or False?
Ans: True

Q. The placard displayed here is used to identify a specific hazardous material. Using your Emergency Response Guidebook (ERG), choose the option that properly identifies this hazardous material
Ans: Sarin

Q. Which types of etiological hazards are the simplest types of microorganisms that can only replicate themselves in the living cells of their hosts?
Ans: Biological agents

Q. Which OSHA requirements pertain to training of hazardous materials responders?
Ans: Title 29 CFR

Q. Who pays for hazmat incident?
Ans: Responsible Party, Local Agencies, State Agencies, Federal Agencies

Q. What type of PPE provides the most limited protection against hazardous materials?
Ans: Structural fire-fighting protective clothing

Q. Who assumes command at a hazmat incident?
Ans: The first responder on the scene or the ranking individual of the first company on the scene

Q. It is safe to enter a site that is oxygen deficient with a concentration of a hazardous material below the Lower Explosive Limit (LEL). True or False?
Ans: False

 

About HAZMAT First Responder Operations (FRO) Test

The HAZMAT First Responder Operations (FRO) test is a requirement for anyone who wants to become a HAZMAT First Responder.

The test is designed to assess the knowledge and skills of individuals who respond to releases or potential releases of hazardous substances as part of the initial response to the site for the purpose of protecting nearby persons, property, or the environment from the effects of the release.

The test covers a wide range of topics, including:

  • Hazard identification and classification
  • Decontamination procedures
  • Emergency response planning
  • Personal protective equipment (PPE)
  • Spill containment and control

To pass the HAZMAT FRO test, you must score a minimum of 70% on each of the five modules.

The test is administered by the National Registry of Emergency Medical Technicians (NREMT).

Applicants must meet certain eligibility requirements, including having a high school diploma or equivalent, completing a HAZMAT First Responder training program, and passing the NREMT First Responder exam.

The NREMT offers practice tests online and in books.

Applicants can study for the HAZMAT FRO test by reviewing the OSHA Hazardous Materials Emergency Response Standard (29 CFR 1910.120), the Emergency Response Guidebook (ERG), and the U.S.

Department of Transportation (DOT) Emergency Response Guide for Shippers and Transporters.

Additionally, many online resources and practice tests are available to help applicants prepare for the exam.

Here are some additional study tips for the HAZMAT FRO test:

  • Form a study group with other HAZMAT First Responder students
  • Ask your instructor for help with any topics that you are struggling with
  • Take advantage of the many online resources that are available
  • Get a good night’s sleep before the test
  • Eat a healthy breakfast on the day of the test
  • Arrive at the testing site early
  • Relax and do your best!

 

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